You can control payment and shipping methods in WooCommerce with B2BKing in the Groups panel. The first step is to go to B2BKing->Groups.
Here you can control available methods for 3 categories of users:
If you click on "Logged Out Users" or "B2C Users", you will see the following panel:
You can check or uncheck options and when you are done, click "Save Settings"
After clicking on "Business Groups", you can then set payment and shipping methods for each user group.
Simply check and uncheck desired options for the specific business group and then click "Update" to save your settings.
If you're not able to see your shipping method in B2BKing ->Groups, it's probably because it uses a non-standard implementation mechanism (not visible as a standard method in WooCommerce -> Settings -> Shipping)
You can try to add the following PHP snippet to the site to see if it can fix it:
}, 10, 1);
The above snippet changes the shipping control mechanism uses by B2BKing from a zone-based mechanism to a non-zone mechanism, and thus different methods will be available. This will help if your shipping method is not added to a particular zone.
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